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dc.contributor.authorTatiana Suárez- Rodríguez, Ángel L. Suárez-Sobrino-
dc.contributor.authorMiguel Tomás-
dc.date.accessioned2016-06-28T10:56:05Z-
dc.date.available2016-06-28T10:56:05Z-
dc.date.issued2013-
dc.identifier.citationJosé Barluenga*, Ana Álvarez-Fernández, Tatiana Suárez-Rodríguez, Ángel L. Suárez-Sobrino, and Miguel Tomás, A Simple Metal-Promoted Three-Step Access to n/5/m Angular Carbocyclic Systems,Org. Lett., 2013, 15 (3), pp 488–491eng
dc.identifier.isbnDOI: 10.1021/ol303269r-
dc.identifier.urihttps://ria.asturias.es/RIA/handle/123456789/6765-
dc.description.abstractA simple three-step access to n/5/m angular tricyclic skeleta from terminal cycloalkenylacetylenes, Cr(CO)6, and propargylmalonate esters is described. The process involves a cyclopentannulation of propargylmalonates and enynyl Fischer carbenes, followed by a metal-promoted Cope-type fragmentation of the propargyl unit. The resulting 4-allenyl-carbonyl derivatives can undergo either a 5-exo annulation via a tin enolate or an unprecedented gold catalyzed 6-endo cyclization.eng
dc.language.isoengeng
dc.publisherACS Publicationseng
dc.relation.ispartofOrganic Letterseng
dc.relation.haspart15eng
dc.relation.hasversion3eng
dc.relation.isreferencedbySí, esta versión ha sido citadaeng
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
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dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/deed.eseng
dc.source488;491-
dc.subjectSíntesis Orgánicaeng
dc.subjectCarbenos de Fischereng
dc.subject.classificationPublicadoeng
dc.titleA Simple Metal-Promoted Three- Step Access to n/5/m Angular Carbocyclic Systemseng
dc.typepostprinteng
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