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Por favor, use este identificador para citar o enlazar este documento: https://ria.asturias.es/RIA/handle/123456789/6781
Título : Zinc-Catalyzed Functionalization of Si-H Bonds with 2-furyl carbenoids through three-component coupling
Autor : López García, Luis Ángel
Vicente Arroyo, Rubén
Palabras clave : Catálisis
Zinc
Fecha de publicación : 26-may-2015
Resumen : A three-component coupling of alk-2-ynals, 1,3-dicarbonyls and silanes is reported. ZnCl2 serves as an inexpensive and low-toxic catalyst for the overall transformation, which involves Knoevenagel condensation, cyclization, and carbene Si[BOND]H bond insertion. The process takes place with high atom economy in the absence of organic solvents and shows a broad scope. This reaction is also applicable to the functionalization of oligomeric siloxanes.
URI : https://ria.asturias.es/RIA/handle/123456789/6781
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Química

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